Citation: Sun Jinyu, Shi Yufang, Liu Chengqi, Zhao Minggen. Synthesis, Theoretical Investigation and Third-Order Nonlinear Optical Properties of Two Chalcone Derivatives[J]. Chemistry, ;2016, 79(10): 975-980. shu

Synthesis, Theoretical Investigation and Third-Order Nonlinear Optical Properties of Two Chalcone Derivatives

1.
Key Laboratory of Materials and Computational Chemistry, Department of Chemistry, Xin Zhou Teachers University, Xin Zhou 034000

Corresponding author: Zhao Minggen,
Received Date: 2 March 2016
Available Online: 20 April 2016
Fund Project:

Two chalcone derivatives 1-(4-methylphenyl)-3-(4-dimethylaminophenyl) acrylic ketone (1) and 1-(4-methylphenyl)-3-(4-methoxyphenyl)acrylic ketone (2) were synthesized and characterized by ¹H NMR, ¹³C NMR, IR and HR-MS. Their third-order nonlinear optical properties were measured by 4f phase-coherent imaging system with pulse width 4nm, laser wavelength 500nm and 440nm, respectively. The relevant parameters were given as follows: for compound 1: the nonlinear absorption coefficient β=7.3×10^-10 m/W, the nonlinear refractive index n₂=-3.6×10^-17 m²/W, the third-order nonlinear polarizability χ⁽³⁾=2.56×10^-11 esu; for compound 2: β= -4.8×10^-10 m/W, n₂=2.0×10^-17 m²/W, χ⁽³⁾=1.45×10^-11 esu. The corresponding UV absorption and DSC curves were also investigated. Moreover, their orbital energy and polarization were calculated by density functional theory. The results indicated that intramolecular electron transfer can occur in 1 and 2. Thus both compounds exhibit better NLO activities.
- Chalcone derivatives,
- Synthesis,
- 4f Phase-coherent imaging system,
- Third-order nonlinear optical properties
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沈阳化工大学材料科学与工程学院沈阳 110142