Citation: Ding Xinru, Huang Xiaodong, Bai Lijun, Yang Jinfei. Green Synthesis of Tetrabromobisphenol A Bis(2,3-dibromopropyl) Ether[J]. Chemistry, ;2016, 79(10): 963-967. shu

Green Synthesis of Tetrabromobisphenol A Bis(2,3-dibromopropyl) Ether

1.
School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210097

Corresponding author: Yang Jinfei,
Received Date: 23 February 2016
Available Online: 30 May 2016
Fund Project:

The addition reaction of alkene with bromine in water was achieved by using 2,2',6,6'-tetrabromobisphenol A diallyl ether as raw materials to synthesize tetrabromobisphenol A bis(2,3-dibromopropyl)ether. All the necessary factors， such as type of additives, amounts of bromine, reaction time and temperature etc., were investigated. The target product was obtained in 93.6% yield (91.7% purity, HPLC) with sodium dodecyl sulfate as accessory ingredient in water. At the same time, the problem of product aggregation caused by poor solubility of raw materials in water was solved. This method has the advantages of simple post-treatments and processing routes, no generation of waste liquids, and low cost, etc.
- Green synthesis,
- Aqueous phase,
- Tetrabromobisphenol A (2,3-dibromopropyl)ether
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沈阳化工大学材料科学与工程学院沈阳 110142