Citation:
Zhang Jiafeng, Wang Li, Sun Yang. Synthesis of Methanol by Microbial Fucl Cell Reverses Reduction of CO2[J]. Chemistry,
;2016, 79(10): 958-962.
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Microbial fuel cell (MFC) reactor makes use of hydrogen-producing microorganisms that attached to the anode to absorb the CO2 Gas, at the same time reversibly turn it into high value biofuels. Fusiform spore fungus Clostridium sp. separated from cow dung was chose as the bacteria for synthesizing biofuels. Cyclic voltammetry test was proceed in MFC reactor by accessing to electrochemical workstation. When reduction reaction occured, the reduction peak appeared at -0.5 V. While using constant voltage DC electrolysis, the synthetic biofuel is methanol. The methanol cumulants come to the maximum of 3.13 mmol/L at 24 h; when CO2 gas proportion is 15%, the maximum methanol cumulants is 2.98 mmol/L. When bacterial inoculum is 1mL, the methanol cumulants reaches the maximum of 2.76 mmol/L. Under the optimum conditions, the CO2 conversion rate is 7.5%.
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