Citation: Wei Xinyu, Wang Shimin, Wei Donghui. A Novel Yellow Phosphorescent Iridium(III) Complex Containing 5-(Trifluoromethyl)-2-pyridinecarboxylic Acid Ligand: Synthesis, Photophysical Properties and Theoretical Calculations[J]. Chemistry, ;2016, 79(10): 947-951. shu

A Novel Yellow Phosphorescent Iridium(III) Complex Containing 5-(Trifluoromethyl)-2-pyridinecarboxylic Acid Ligand: Synthesis, Photophysical Properties and Theoretical Calculations

1.
1. Shangqiu Supervision & Testing Center for Quality and Technology, Shangqiu 476000;
2.
2. Department of Materials and Chemical Engineering, Henan Institute of Engineering, Zhengzhou 451191;
3.
3. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001

Corresponding author: Wang Shimin,
Received Date: 11 March 2016
Available Online: 21 April 2016
Fund Project:

An iridium complex[Ir(dfpmpy)₂(tfmpic)] with 2-(2',4'-difluorophenyl)-4-methylpyridine (dfpmpy) as cyclometalated ligand and 5-(trifluoromethyl)-2-pyridinecarboxylic acid (tfmpic) as ancillary ligand has been prepared, and its photophysical and electrochemical properties have been investigated. In degassed CH₃CN solution, this complex exhibits yellow light emission with a peak wavelength of 554 nm, which was attributed to the ³MLCT or ³LLCT states.
- 5-(Trifluoromethyl)-2-pyridinecarboxylic acid,
- Iridium complex,
- Yellow light emission
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沈阳化工大学材料科学与工程学院沈阳 110142