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Citation: Zhang Weide, Sha Kaiqing, Yu Lajia, Wan Huilin, Tsai Khirui. Oxidative Dehydrogenation of Propane on Supported V₂O₅/Zr₃(PO₄)₄ Catalysts[J]. Chinese Journal of Applied Chemistry, ;1999, 16(1): 34-37. shu

Oxidative Dehydrogenation of Propane on Supported V₂O₅/Zr₃(PO₄)₄ Catalysts

1.
Department of Chemistry, State Key Laboratory for Physical Chemistry of Solid Surface and Institute of Physical Chemistry, Xiamen University, Xiamen 361005

Received Date: 19 May 1998
Available Online: 24 September 1998
Fund Project: 国家自然科学基金(29392006) (29392006)

0.6%~6.0%V₂O₅ were supported on the amorphous Zr₃(PO₄)₄ by a impregnation method. The supported catalysts were effective in the oxidative dehydrogenation of propane, e.g. on a 3.0%V₂O₅/Zr₃(PO₄)₄ catalyst propene had selectivity of 53.8% at a propane conversion of 17.0% and the yield of propene was 9.1%. XRD, IR and Raman results showed that the vanadium oxide was distributed on the support in form of VO_x species. ESR results indicated there are V⁴⁺ species in the catalysts, implying that the oxidation couple of V⁵⁺/V⁴⁺ could be responsible for the redox reaction in propane oxidative dehydrogenation.
- propane,
- oxidative dehydrogenation,
- zirconium phosphate support,
- supported vanadium based catalyst
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Oxidative Dehydrogenation of Propane on Supported V₂O₅/Zr₃(PO₄)₄ Catalysts