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Citation: Tang Hong, Xu Shouyi. Synthesis of Transcyclohexane Carboxylic Acid Derivatives[J]. Chinese Journal of Applied Chemistry, ;1999, 16(2): 85-87. shu

Synthesis of Transcyclohexane Carboxylic Acid Derivatives

Tang Hong ,
Xu Shouyi

1.
Department of Chemistry, Tsinghua University, Beijing 100084

Received Date: 10 September 1998
Available Online: 8 December 1998

Selective reduction of the phenyl ring beared carboxyl group was realized successfully with sodium and amyl alcohol at 140~145℃.Through cis-trans isomerization trans-4-(4'-pentylphenyl) cyclohexyl carboxylic acid and trans-4'[2'-(4"-pentylphenyl) ethylene]cyclohexyl carboxylic acid were obtained in good yield and their structures were characterized by elemental analysis,IR,¹³C NMR and MS measurements.
- trans cyclohexane carboxylic acid derivative,
- cis-trans isomerization,
- selective reduction,
- liquid crystal material,
- synthesis
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