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Citation: Kang Jingw an, Geng Zaixin, Lu Xiaoquan, Zhou Xibin, Gao Jinzhang. Synthesis and Electrochemical Behavior of Symmetrical Nickel Porphyrins[J]. Chinese Journal of Applied Chemistry, ;1999, 16(3): 73-75. shu

Synthesis and Electrochemical Behavior of Symmetrical Nickel Porphyrins

1.
Institute of Chemistry, Northwest Normal University, Lanzhou 730070

Received Date: 29 September 1998
Available Online: 23 March 1999
Fund Project: 甘肃省自然科学基金资助课题(ZS981-A25-009-Z) (ZS981-A25-009-Z)

Tetra(4-hydroxyphenyl) porphyrin(THPPH₂) was synthesized by condensation of 4-hydroxybenzaldehyde and pyrrole in DMF using anhydrous AlCl₃ as catalyst without neccessity to use inert gas for protection. Its nickel complex(THPPNi) and Ni meso-tetra(4-benzoxyphenyl) porphyrin(TBOPPNi), Ni meso-tetra[4-(carboxymethylenoxy)phenyl] porphyrin(TCMOPPNi) were also prepared. Their structures were ascertained by elemental analysis, visible spectrum, IR and ¹H NMR measurements. The electrochemical property of TCMOPPNi has been investigated in DMSO by cyclic voltammetry and differential pulse voltammetry.
- nickel porphyrin,
- synthesis,
- characterization,
- electrochemical property
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