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Citation: Xie Xuepeng, Xian Chunying, Zhu Longguan, Yu Qingsen. Synthesis and Crystal Structure of Quaternary Mixed Anion Complexes of [Ln(CH₃COO)₂(NO₃)(bipy)]₂[J]. Chinese Journal of Applied Chemistry, ;1999, 16(3): 41-44. shu

Synthesis and Crystal Structure of Quaternary Mixed Anion Complexes of [Ln(CH₃COO)₂(NO₃)(bipy)]₂

1.
Department of Chemistry, Zhejiang University, Hangzhou 310027

Received Date: 23 December 1998
Available Online: 23 March 1999

Five quaternary mixed anion complexes of lanthanide [Ln(CH₃COO)₂(NO₃)(bipy)]₂ (Ln=Pr,Nd,Sm,Eu,Gd), were synthesized and studied by IR, UV, DTA-TG, fluorescence spectrum and ESR measurements. It belongs to triclinic system with space group P1, a=0.8329(1) nm, b=0.8975(1) nm, c=1.2837(1),α=109.85(1)°, β=104.35(1)°, γ=99.15(1)°, V=0.8426(4) nm³, Z=2, M_r=477.19, D_c=1.881 g/cm, μ=2.921 mm^-1, F(000)=468. The four acetates have two coordinated modes. Two acetates are bridged and the others are trio-coordinate.
- lanthanide,
- quaternary complex,
- synthesis,
- crystal structure
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Synthesis and Crystal Structure of Quaternary Mixed Anion Complexes of [Ln(CH3COO)2(NO3)(bipy)]2

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Synthesis and Crystal Structure of Quaternary Mixed Anion Complexes of [Ln(CH₃COO)₂(NO₃)(bipy)]₂