Home

Citation: Yan Lijing, Lin Haichao, Wu Weitao. Effect of Hydrogen Sulfide on the Inhibition Action of Propargyl Alcohol in Fe/H₂SO₄ System[J]. Chinese Journal of Applied Chemistry, ;1999, 16(3): 1-4. shu

Effect of Hydrogen Sulfide on the Inhibition Action of Propargyl Alcohol in Fe/H₂SO₄ System

1.
Institute of Corrosion and Protection of Metals, State Key Laboratory for Metal Corrosion and Protection, Chinese Academy of Sciences, Shenyang 110015

Received Date: 9 October 1998
Available Online: 17 March 1999
Fund Project: 国家自然科学基金资助项目(59571058) (59571058)

The effect of H₂S on the inhibition action of propargyl alcohol(PA) in Fe/H₂SO₄ system has been investigated by electrochemical potentiodynamic and potentiostatic methods. The results showed that PA could inhibit the anodic and cathodic reactions of iron corrosion effectively in H₂SO₄ solution containing H₂S. At low content of PA the inhibition efficiency decreased with the increase of H₂S content due to the strong interaction of H₂S and HS^- with Fe. At high content of PA, Fe(HS^-)_ads is stabilized owing to the hydrogen bonds and electrostatic action, which made the anodic current approach to zero. The interaction between PA and Fe(H₂S)_ads in this case is weak.
- iron corrosion,
- propargyl alcohol,
- H₂S,
- inhibition effect
1. [1]
  Xingyu Liao , Xiangming Yi , Kin Shing Chan . 追凶之路上的怪客——硫化氢. University Chemistry, 2025, 40(6): 172-176. doi: 10.12461/PKU.DXHX202408039
2. [2]
  Linfang ZHANG , Wenzhu YIN , Gui YIN . A 2-dicyanomethylene-3-cyano-4,5,5-trimethyl-2,5-dihydrofuran-based near-infrared fluorescence probe for the detection of hydrogen sulfide and imaging of living cells. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 540-548. doi: 10.11862/CJIC.20240405
3. [3]
  Jichao XU , Ming HU , Xichang CHEN , Chunhui WANG , Leichen WANG , Lingyi ZHOU , Xing HE , Xiamin CHENG , Su JING . Construction and hydrogen peroxide-activated chemodynamic activity of ferrocene?benzoselenadiazole conjugate. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1495-1504. doi: 10.11862/CJIC.20250144
4. [4]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 2408004-0. doi: 10.3866/PKU.WHXB202408004
5. [5]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
6. [6]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
7. [7]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
8. [8]
  Yiling Wu , Peiyao Jin , Shenyue Tian , Ji Zhang . The Star of Sugar Substitutes: An Interview of Erythritol. University Chemistry, 2024, 39(9): 22-27. doi: 10.12461/PKU.DXHX202404034
9. [9]
  Shuyong Zhang , Shu'e Song . Ideological and Political Case Design of Experiment of Corrosion and Protection Linking with National Major Projects. University Chemistry, 2024, 39(2): 57-60. doi: 10.3866/PKU.DXHX202304078
10. [10]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
11. [11]
  Aili Feng , Xin Lu , Peng Liu , Dongju Zhang . Computational Chemistry Study of Acid-Catalyzed Esterification Reactions between Carboxylic Acids and Alcohols. University Chemistry, 2025, 40(3): 92-99. doi: 10.12461/PKU.DXHX202405072
12. [12]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
13. [13]
  Yixuan Wang , Canhui Zhang , Xingkun Wang , Jiarui Duan , Kecheng Tong , Shuixing Dai , Lei Chu , Minghua Huang . Engineering Carbon-Chainmail-Shell Coated Co₉Se₈ Nanoparticles as Efficient and Durable Catalysts in Seawater-Based Zn-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2305004-0. doi: 10.3866/PKU.WHXB202305004
14. [14]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
15. [15]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
16. [16]
  Yifeng TAN , Ping CAO , Kai MA , Jingtong LI , Yuheng WANG . Synthesis of pentaerythritol tetra(2-ethylthylhexoate) catalyzed by h-MoO₃/SiO₂. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2155-2162. doi: 10.11862/CJIC.20240147
17. [17]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
18. [18]
  Yuanyuan Ping , Wangqing Kong . 光催化碳氢键官能团化合成1-苯基-1,2-乙二醇. University Chemistry, 2025, 40(6): 238-247. doi: 10.12461/PKU.DXHX202408092
19. [19]
  Mengyang LI , Hao XU , Zhonghao NIU , Chunhua GONG , Weihui ZHONG , Jingli XIE . Highly effective catalytic synthesis of β-amino alcohols by using viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1294-1300. doi: 10.11862/CJIC.20250080
20. [20]
  Yinjie Xu , Suiqin Li , Lihao Liu , Jiahui He , Kai Li , Mengxin Wang , Shuying Zhao , Chun Li , Zhengbin Zhang , Xing Zhong , Jianguo Wang . Enhanced Electrocatalytic Oxidation of Sterols using the Synergistic Effect of NiFe-MOF and Aminoxyl Radicals. Acta Physico-Chimica Sinica, 2024, 40(3): 2305012-0. doi: 10.3866/PKU.WHXB202305012

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(431)
HTML views(69)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return

Effect of Hydrogen Sulfide on the Inhibition Action of Propargyl Alcohol in Fe/H2SO4 System

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of Hydrogen Sulfide on the Inhibition Action of Propargyl Alcohol in Fe/H₂SO₄ System