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Citation: Yang Yiquan, Wang Qi, Dai Shenjun, Yuan Youzhu, Lin Rencun, Zhang Hongbin. Preparation of Mo-S-based Catalysts for Methanthiol Synthesis from High H₂S-containing Syngas[J]. Chinese Journal of Applied Chemistry, ;1999, 16(4): 47-51. shu

Preparation of Mo-S-based Catalysts for Methanthiol Synthesis from High H₂S-containing Syngas

1.
Department of Chemistry, Institute of Physical Chemistry, State Key Laboratory for Physical Chemistry of Solid Surface, Xiamen University, Xiamen 361005

Received Date: 30 November 1998
Available Online: 23 April 1999
Fund Project: 国家自然科学基金资助项目(29673034) (29673034)

The catalytic performance of Mo-S-K-based catalysts prepared with different precursors for synthesis of methanthiol from high H₂S containing syngas has been investigated. The effects of the promotors K₂CO₃, KCl and KF on the activity of the catalyst under various temperature and pressure conditions have been examined. The results show that MoS₂/K₂CO₃/γ-Al₂O₃ catalyst prepared with precursor (NH₄)₂MoS₄ was found to have the same catalytic behavoir as that prepared from K₂MoS₄. XRD measurements indicate the existence of a new Mo-S-K phase (2θ=29.8° and 30.8°) in the catalyst both of MoS₂/K⁺/γ-Al₂O₃ promoted by weak basic potassium salts (K₂CO₃ and KF) and of K₂MoS₄/γ-Al₂O₃ respectively.
- Mo-S-based catalyst,
- H₂S containing syngas,
- methanthiol,
- preparation
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沈阳化工大学材料科学与工程学院沈阳 110142

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Preparation of Mo-S-based Catalysts for Methanthiol Synthesis from High H2S-containing Syngas

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Preparation of Mo-S-based Catalysts for Methanthiol Synthesis from High H₂S-containing Syngas