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Citation: WANG Peng, ZHU Guo-Yi. Synthesis, Characterization and Electrochemical Behavior of Hydrophobic Phenanthroline Iron(Ⅱ)Complexes[J]. Chinese Journal of Applied Chemistry, ;2000, 17(1): 6-10. shu

Synthesis, Characterization and Electrochemical Behavior of Hydrophobic Phenanthroline Iron(Ⅱ)Complexes

WANG Peng ,
ZHU Guo-Yi

1.
Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 20 July 1999
Available Online: 16 October 1999
Fund Project: 国家科学技术部"九五"攻关重点项目资助课题(96-A23-03-01) (96-A23-03-01)

Four hydrophobic phenanthroline iron(Ⅱ)complexes, tris(5-lauramido-1, 10-phenanthroline) iron (Ⅱ) perchlorate, tris (5-myristamido-1, 10-phenanthroline) iron (Ⅱ) perchlo rate, tris (5-palmitamido-1, 10-phenanthroline)iron (Ⅱ) perchlo rate and tris (5-stearamido-1, 10-phenanthroline) iron(Ⅱ) perchlorate, have been sy nthesized and characterized by elemental analysis, IR, ¹H NMR, ¹H-¹H COSY and LD-MS. ¹H NMR spectra of these complexes showed that each of them exists in two isomers in relative proportion of 1:1. The electrochemical behavior of these Fe(Ⅱ) complexes have been investigated with cyclic voltammetry and square-wave voltammetry.
- hydrophobic phenanthroline iron(Ⅱ)complex,
- synthesis,
- ¹H NMR,
- cyclic voltammetry,
- square-wave voltammetry
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