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Citation: ZHANG Yu-Chuan, TIAN Yu-Peng, XU Hong-Yao, XIE Fu Xin, XIA Ru. Synthesis and Coordination Property Studies of Tetraazamacrocyclics Attached on Polymer[J]. Chinese Journal of Applied Chemistry, ;2000, 17(2): 142-145. shu

Synthesis and Coordination Property Studies of Tetraazamacrocyclics Attached on Polymer

1.
Department of Chemistry, Anhui University, Hefei 230029

Received Date: 27 August 1999
Available Online: 21 December 1999
Fund Project: 国家自然科学基金(29871001) (29871001)

Two tetraazamacrocyclics: 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclote-tradecane (Me₆[14]N₄) and 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-N-acetic acid(Me₆[14]N₄CH₂COOH) were synthesized and attached covalently to chlormeth-atedyl polystyrene bead both in gel and macropore type, respectively. The four polymer macrocyclic ligands(A,A^*,B,B^*) thus obtained showed a good coordination ability and their coordination capacities and selectivity properties towards Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ), and Zn(Ⅱ) were studied. The coordinated metal ion could be easily leached out by dilute hydro-chloric acid from the polymeric macrocyclic ligands and the latter could be used repeatedly.
- tetraazamacrocyclic,
- tetraazamacrocyclic-N-acetic acid,
- chlormethylated polysty-rene,
- transition metal,
- polymeric macrocyclic complex
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