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Citation: LIU Shu-Qing, SUN Hao-Ran, XU Ji-Qing, LI Dong-Mei. Synthesis and Characterization of Meso-Tetrakis (4-pyridyl)porphyrin Derivatives[J]. Chinese Journal of Applied Chemistry, ;2000, 17(3): 260-263. shu

Synthesis and Characterization of Meso-Tetrakis (4-pyridyl)porphyrin Derivatives

1.
Department of Chemistry, Jilin University, Changchun 130023

Received Date: 12 October 1999
Available Online: 14 March 2000
Fund Project: 国家自然科学基金(29733090,29803003) (29733090,29803003)

Four cationic meso-tetrakis(4-N-pyridyl)porphyrin derivatives 5,10,15,20 tetra kis (4-N-benzylpyridyl)porphyrin(H₂TBPyP), 5,10,15,20-tetrakis(4-N-propylpyridyl)porphyrin(H₂TPPyP), 5,10,15,20 tetrakis(4-N-ethylpyridyl)porphyrin(H₂TEPyP), 5,10,15,20-tetrakis(4-N-methylpyridyl)porphyrin(H₂TMPyP), and their cobalt complexes have been synthesized. Some of the porphyrin compounds were characterized by elemental analysis, matrix-assisted laser desorption/ionization time of flight-mass spectrometry(MALDI-TOF-MS), UV-Vis, FTIR, ¹H NMR and cyclic voltammetry.
- cationic porphyrin,
- complex,
- synthesis,
- reductive potential
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