Citation:
CHENG Ge, WANG Yue-Chuan. Synthesis of Oligophenylene Dendrimer Catalyzed by Ligandless Palladium Chloride[J]. Chinese Journal of Applied Chemistry,
;2000, 17(4): 462-464.
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A dendritic oligophenylene in yield of 48% has been synthesized via cross coupling reaction of phenyl boronic acid with 1,3,5-tris(3,5-dibromophenyl)benzene catalyzed by the ligandless palladium chloride in mixture of water/toluene/THF in the presence of tetrabutylammonium bromide. The yield per coupling(y/c) was 88%.
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