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Citation: PAN Na, YU Hui, JIANG Jian-Zhuang. IR Spectral Characteristics of Substituted Phthalocyanine and Its Sandwich-Type Neodymium Double- and Triple-Decker Complexes[J]. Chinese Journal of Applied Chemistry, ;2000, 17(4): 409-410. shu

IR Spectral Characteristics of Substituted Phthalocyanine and Its Sandwich-Type Neodymium Double- and Triple-Decker Complexes

1.
College of Chemistry and Environmental Science, Shandong University, Ji'nan 250100

Received Date: 2 December 1999
Available Online: 30 March 2000
Fund Project: 国家自然科学基金(29701002) (29701002)教育部优秀青年教师基金,教育部骨干教师基金,山东省优秀中青年科学家奖励基金,山东省自然科学基金重点(Z99B03)资助项目 (Z99B03)

An assignment of the IR bands for a free substituted phthalocyanine H₂[Pc-(OC₈H₁₇)₈], its sandwich-type neodymium(Ⅲ) double- and triple-decker complex, Nd[Pc(OC₈H₁₇)₈]₂ and (Pc)Nd[Pc(OC₈H₁₇)₈]Nd[Pc(OC₈H₁₇)₈] has been done. It is found that in H₂[Pc(OC₈H₁₇)₈] and (Pc)Nd[Pc(OC₈H₁₇)₈]Nd[Pc(OC₈H₁₇)₈] the characteristic IR peaks appeared at 1330 cm^-1(w), 1380 cm^-1(s) and 1070~1080 cm^-1 (rs) for bivalent phthalocynine anions: Pc^2- or Pc(OC₈H₁₇)₈^2-, and in Nd[Pc(OC₈H₁₇)₈]₂ the characteristic peaks appeared at 1315 cm^-1 (rs) and 1380 cm^-1 (s) were assigned for single phthalocyanine anion free radical.
- sandwich phthalocyanine complex,
- neodymium complex,
- infrared spectrum
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