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Citation: LIU Ying, ZUO Xia, WU Yi-Qun, ZHU Qing-Tao, CHEN Nai-Sheng, SONG Yin-Lin, FANG Guang-Yu. Synthesis of Tetrabromo-2,3-naphthophthalocyanine Zinc(Ⅱ) and Its Nonlinear Optical Limiting[J]. Chinese Journal of Applied Chemistry, ;2000, 17(5): 569-571. shu

Synthesis of Tetrabromo-2,3-naphthophthalocyanine Zinc(Ⅱ) and Its Nonlinear Optical Limiting

1.
a Department of Chemistry, Helongjiang University, Harbin 150080;
2.
b Department of Applied Physics, Harbin Institute of Technology, Harbin

Received Date: 17 November 1999
Available Online: 30 May 2000

Tetrabromo-2,3-naphthophthalocyanine zinc(Ⅱ)(ZnNcBr₄) was synthesized by refluxing 6-bromo-2,3-dicyanonaphthlene with anhydrous zinc chloride in n-amyl alcohol in the presence of 1,8-diazabicyclo[5,4,0]-undec-7-ene. The product was characterized by elemental analysis and IR. The absorption spectra in non-aqueous solvents and the thermal stability of the compound were studied. Its nonlinear optical limiting was explored by a double frequency Nd:YAG pulse laser system with wavelenth of 532 nm and pulse width of 8 ns and 23 ps.
- tetrabromo-naphthophthalocyanine zinc(Ⅱ),
- synthesis,
- nonlinear optical limiting
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