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Citation: PAN Chun-Yue, HU Hui-Pin, MA Cheng-Yin, HUANG Ke-Long, HUANG Yong-Li. Emulsion Polymerization of Aniline[J]. Chinese Journal of Applied Chemistry, ;2000, 17(5): 491-494. shu

Emulsion Polymerization of Aniline

1.
College of Chemistry and Chemical Engineering, Central South University of Technology, Changsha 410083

Received Date: 20 December 1999
Available Online: 22 May 2000
Fund Project: 湖南省自然科学基金资助项目(98JJY2060) (98JJY2060)

The emulsion polymerization of aniline in a system consisted of non-polar or weakly polar solvent, functionized protonic acid and water was carried out using (NH₄)₂ S₂O₈ as oxidant. The effects of emulsion polymerization conditions:doping acid, oxidant, reaction time and temperature, water content on the solubility, conductivity and yield of polyaniline were studied. The polyaniline synthesized shows much higher solubility in organic solvents than those synthesized by chemical oxidation polymerization. The PAn-DBSA (dodecylbenzene sulfonic acid) obtained in yield of 80% with conductivity over 1 S/cm.
- aniline,
- emulsion polymerization,
- solubility
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