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Citation: LU Jun-Rui, WANG Ya-Lin, FENG Yan, GU Ling. Synthesis of 4,4'-Dinitrodibenzyl and 4,4'-Dinitrostilbene[J]. Chinese Journal of Applied Chemistry, ;2000, 17(6): 651-653. shu

Synthesis of 4,4'-Dinitrodibenzyl and 4,4'-Dinitrostilbene

LU Jun-Rui ^a ,
WANG Ya-Lin ^a ,
FENG Yan ^a ,
GU Ling ^b

1.
a Department of Chemical Engineering, Tianjin Institute of Science and Technology, Tianjin 300191;
2.
b Tianjin Worker's Chemical Engineering College, Tianjin

Received Date: 17 January 2000
Available Online: 6 June 2000
Fund Project: 天津市21世纪青年科学基金资助项目(973701611) (973701611)

The title compounds were synthesized by oxidative dimerization of p-nitrotoluene. The effects of solvents, bases and oxidizing agents on the dimerization were investigated. The results showed that by selecting appropriate solvents, oxidizing agents, base catalysts and controlling technical conditions the yields of dinitrodibenzyl and dinitrostilbene could be reached 89.4% and 74.6%, respectively.
- dinitrobenzyl,
- dinitrostilbene,
- synthesis,
- nitrotoluene,
- oxidative dimerization
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