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Citation: JIANG Peng, LÜ Shi-Jie. Synthesis of Poly(Cinchona alkaloid-co-methyl acrylate)s and Their Hydrolysates for Asymmetric Hydrogenation[J]. Chinese Journal of Applied Chemistry, ;2000, 17(6): 639-641. shu

Synthesis of Poly(Cinchona alkaloid-co-methyl acrylate)s and Their Hydrolysates for Asymmetric Hydrogenation

JIANG Peng ,
LÜ Shi-Jie

1.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000

Received Date: 26 January 2000
Available Online: 31 May 2000
Fund Project: 国家自然科学基金资助项目(29933050) (29933050)

The title copolymers and their water soluble carboxylates were synthesized from methyl acrylate and cinchonine, quinine in CHCl₃, respectively, using azo-bis-isobutyroni-trile as initiator. The four compounds as chiral amine ligands being reacted with dimethylglyoximatocobalt(Ⅱ) gave four complexes, which were used for catalytic asymmetric hydrogenation of acetamidocinamic acid, giving considerably possitive results.
- poly(cinchonine(quinine)-co-methyl acrylate),
- dimethylglyoximatocobalt(Ⅱ),
- asymmetric hydrogenation
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