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Citation: ZHONG Shun-He, GU Xiu-Jun, LI Xing-Bo, XIAO Xiu-Fen. Fe_1/2Al_1/2PO₄ Catalyst for Preparation of Propylene Oxide from 1,2-Dichloropropane[J]. Chinese Journal of Applied Chemistry, ;2001, 18(1): 81-83. shu

Fe_1/2Al_1/2PO₄ Catalyst for Preparation of Propylene Oxide from 1,2-Dichloropropane

1.
College of Chemical Engineering, Tianjin University, Tianjin 300072

Received Date: 13 March 2000
Available Online: 29 August 2000

The title catalyst was prepared by the sol-gel method. The surface composite, structure, specific area and catalytic behavior have been investigated by IR, BET, XRD, TEM techniques. The results showed that the catalyst is an amorphous composed of FePO₄ and AlPO₄ with specific area about 238 m²/g and average granule size less than 10 nm. Under proper reaction conditions the conversion of 1,2-dichloropropane was more than 64% and the selectivity to propylene oxide was more than 79%.
- dichloropropane,
- dechlorination,
- oxidation,
- propylene oxide,
- Fe_1/2Al_1/2PO₄
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Fe1/2Al1/2PO4 Catalyst for Preparation of Propylene Oxide from 1,2-Dichloropropane

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Fe_1/2Al_1/2PO₄ Catalyst for Preparation of Propylene Oxide from 1,2-Dichloropropane