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Citation: LIU Wei, SHI Tong-Shun. Fourier Transform Infrared Photoacoustic Spectra of Transition Metal Complexes of Meso-tetra-(4-lauroyloxyphenyl)porphyrin[J]. Chinese Journal of Applied Chemistry, ;2001, 18(1): 59-61. shu

Fourier Transform Infrared Photoacoustic Spectra of Transition Metal Complexes of Meso-tetra-(4-lauroyloxyphenyl)porphyrin

LIU Wei ,
SHI Tong-Shun

1.
Department of Chemistry, Jilin University, Changchun 130023

Received Date: 10 March 2000
Available Online: 12 June 2000
Fund Project: 国家自然科学基金资助课题(59783001) (59783001)

The fourier transform infrared photoacoustic spectra of meso-tetra-(4-lauroyloxyphenyl)porphyrin(TLPPH₂) and its complexes with Mn (Ⅲ)、Fe (Ⅲ)、Co (Ⅱ)、Ni (Ⅱ)、Cu (Ⅱ) and Zn (Ⅱ) in the range of 3600~190 cm^-1 were measured and investigated. The bands at 3318 and 968 cm^-1 of TLPPH₂ are due to the N-H stretching and in-plane and out of plane bending vibration of the pyrrole groups. All these bands disappear upon complex formation. The vibration coupling between the M-N stretching and the porphyrin ring deformation appears at 250 cm^-1. Metal sensitive bands were found at 1354、1018、983、796、736、632、231 cm^-1.
- meso-tetra-(lauroyloxyphenyl) porphyrin,
- metalloporphyrin,
- infrared photoacoustic spectrum
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