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Citation: YAN Yan, ZHENG Guo-Dong, CHEN Yu-Qin, ZHEN Kai-Ji, FANG Chi-Guang, WANG Ao, LI Qing, CHANG Xin. Preparation of 2-Hydroxyl-1,4-naphthoquinone by Catalytic Oxidation of Naphthol over Iron Porphyrin[J]. Chinese Journal of Applied Chemistry, ;2001, 18(1): 29-31. shu

Preparation of 2-Hydroxyl-1,4-naphthoquinone by Catalytic Oxidation of Naphthol over Iron Porphyrin

YAN Yan ^a,b ,
ZHENG Guo-Dong ^a,b ,
CHEN Yu-Qin ^a ,
ZHEN Kai-Ji ^a,b ,
FANG Chi-Guang ^c ,
WANG Ao ^c ,
LI Qing ^c ,
CHANG Xin ^c

1.
a Department of Chemistry, Jilin University, Changchun 130023;
2.
b Technical School for Municipal Facilties, Changchun;
3.
c Jilin Provincial Health and Anti-epidemic Station, Changchun

Received Date: 29 February 2000
Available Online: 4 September 2000
Fund Project:

The 2-hydroxyl-1, 4-naphthoquinone(HNQ) was prepeared by catalytic oxidation of 1-naphthol and/or 2-naphthol in NaOH methanol solution with H₂O₂ over 5,10,15,20 tetra(4-methoxyl)phenyl porphyrin iron chloride in yield of 57% and purity of 95%. The UV-Vis, IR, NMR, MS, mp determination and elemental analysis were used for characterization. A spectro photometric method was proposed for quantitative analysis of HNQ using λ_max=452 nm.
- naphthol,
- catalytic oxidation,
- iron porphyrin,
- hydroxy-naphthoquinone
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