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Citation: CAI Chun, LÜ Chun-Xu. Catalytic Dehydrogenation over Pd-Supported ZSM-5 Zeolite for o-Phenylphenol Synthesis[J]. Chinese Journal of Applied Chemistry, ;2001, 18(2): 167-168. shu

Catalytic Dehydrogenation over Pd-Supported ZSM-5 Zeolite for o-Phenylphenol Synthesis

CAI Chun ,
LÜ Chun-Xu

1.
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094

Received Date: 25 May 2000
Available Online: 5 September 2000

Pd-supported ZSM-5 zeolites prepared through ion exchange technique were used as a dehydrogenation catalyst for synthesis of o-phenylphenol from cyclohexanone. When Si/Al ratio in the catalyst was 85:1 or more, an obvious reduction in attenuation rate of catalyst activity was observed. When the Si/Al ratio was of 17:1 or less, polymer compounds could be formed on the surface of zeolite, that would decrease the dehydrogenation activity due to the reduction of the specific surface area of the catalyst.
- o-phenylphenol,
- cyclohexanone,
- catalytic dehydrogenation,
- zeolite
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