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Citation: YAN Hong-Xia, NING Rong-Chang, MA Xiao-Yan. Preparation of Phosphorus Nitride Dichloride Oligomers[J]. Chinese Journal of Applied Chemistry, ;2001, 18(2): 163-164. shu

Preparation of Phosphorus Nitride Dichloride Oligomers

1.
Department of Chemistry Engineering, Northwestern Polytechnical University, Xi'an 710072

Received Date: 14 April 2000
Available Online: 22 September 2000
Fund Project:

Hexachlorocyclotriphosphazene was prepared by reacting ammonium chloride and phosphorus pentachloride in an inert organic solvent at the presence of different metal compounds and pyridine. The conbination of MgCl₂·6H₂O with pyridine showed an ideal catalytic activity to give hexachlorocyclotriphosphazene in yield of 87% under the suitable conditions. The method is time saving.
- hexachlorocyclotriphosphazene,
- ammonium chloride,
- phosphorus pentachloride,
- synthesis
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