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Citation: GAO Shan, LIU Shi-Xiong. Synthesis and Characterization of Dinuclear Vanadyl Hydrazone Complex[VO(C₁₄H₁₀N₂O₂)]₂(μ-O)[J]. Chinese Journal of Applied Chemistry, ;2001, 18(2): 161-162. shu

Synthesis and Characterization of Dinuclear Vanadyl Hydrazone Complex[VO(C₁₄H₁₀N₂O₂)]₂(μ-O)

GAO Shan ^a,b ,
LIU Shi-Xiong ^a

1.
a Department of Chemistry, Fuzhou University, Fuzhou;
2.
b College of Chemistry and Technology, Heilongjiang University, Harbin 150080

Received Date: 19 April 2000
Available Online: 4 September 2000
Fund Project: 福建省自然科学基金(B97006) (B97006)

The dinuclear complex[VO(L)]₂(_-O)(H₂ L=salicylaldehyde benzoylhydrazone) was synthesized and characterized by elemental analysis, IR, UV, cyclic voltammetry. The results showed that two oxygen atoms and one nitrogen atom of the tridentate hydrazone ligand are coordinated to vanadium(V) atom. The vanadium atom approximates to a distorted square pyramidal coordination sphere. The redox potentials of the title complex in different solvents follow the order:CH₂Cl₂< CH₃CN< DMF.
- oxovanadium(V) complex,
- hydrazone,
- synthesis,
- redox property
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Synthesis and Characterization of Dinuclear Vanadyl Hydrazone Complex[VO(C₁₄H₁₀N₂O₂)]₂(μ-O)