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Citation: LIU Yong-Hong, LIU Xiao-Lan, LEI Xin-You, LIU Liu, WANG Yun-Pu. Synthesis and Hydroformylation Activity of Benzylidyne Noncarbonyl-tricobalt Complexes with Triphenylphosphine(Arsine,Stibine,Bismuthine)[J]. Chinese Journal of Applied Chemistry, ;2001, 18(2): 146-148. shu

Synthesis and Hydroformylation Activity of Benzylidyne Noncarbonyl-tricobalt Complexes with Triphenylphosphine(Arsine,Stibine,Bismuthine)

1.
a Department of Chemistry, Tianshui Normal College, Tianshui 741000;
2.
b College of Chemistry and Chemical Engineering, Northwest Teacher's College, Lanzhou

Received Date: 18 July 2000
Available Online: 25 September 2000

Eight metal cluster compounds have been synthesized from parent compound (_₃-CPh)Co₃-(CO)₉ and triphenylphosphine(arsine,stibine,bismuthine). All the compounds were characterized by elemental analysis and IR spectrometry. They results showed that their catalytic activities for 1-butene hydroformylation and the yields of product both were higher than that of the parent compound in 97% and 20% more, respectively, at reaction conditions of 303.5 K, 0.392 MPa, and for 48 hours. The catalytic activities and the ratio of nor to iso by using PhCCo₃(CO)₇(APh₃)_m were increased with increase in the atomic numbers of element A(A=P,As,Sb,Bi).
- benzylidyne noncarbon-tricobalt,
- triphenyl phosphine,
- hydroformylation
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