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Citation: JIAO Qing-Ze, GUO Jun, JIANG Da-Zhen, HE Yi-Gong, MIN En-Ze. Alkylation of Isobutane with Butene over Tungstophosphoric Acid Pillar Double Hydroxides[J]. Chinese Journal of Applied Chemistry, ;2001, 18(2): 137-139. shu

Alkylation of Isobutane with Butene over Tungstophosphoric Acid Pillar Double Hydroxides

1.
a Department of Chemistry, Jilin University, Changchun 130023;
2.
b Research Institute of Petroleum Processing, Beiling

Received Date: 5 July 2000
Available Online: 5 October 2000

Tungstophosphoric acid pillar double hydroxides with composition of M₂Al-PW₁₂[M=Zn²⁺,Co²⁺,Ni²⁺,Mg²⁺] have been synthesized and their catalytic activities for isobutane-butene alkylation were studied. The results showed that M₂Al-PW₁₂ had higher initial activity and selectivity of product, but lower deactivation rate than parent H₃PW₁₂ and the activity of the catalysts and selectivity in alkylation appeared in relation with the kinds of elements in double hydroxide.
- isobutane,
- butene,
- alkylation,
- tungstophosphoric acid,
- layered compound
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