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Citation: ZHANG Wang-Qing, SHI Lin-Qi, DU Man-Quan, YIN Fen-Fang, HE Bing-Lin, GAO Li-Chao, GAO Jun-Gang. Atom Transfer Radical Polymerization of GMA at Room Temperature[J]. Chinese Journal of Applied Chemistry, ;2001, 18(5): 370-372. shu

Atom Transfer Radical Polymerization of GMA at Room Temperature

1.
a State Key Laboratory of Functional Polymer Materials for Adsorption and Separation Institute of Polymer Chemistry, Nankai University, Tianjin 300071;
2.
b Department of Chemistry, Hebei University, Baoding

Received Date: 20 January 2001
Available Online: 12 March 2001
Fund Project: 国家自然科学基金资助(59873012) (59873012)

Atom transfer radical polymerization (ATRP) of glycidyl methacrylate (GMA) at room temperature was carried out in a methylethyl ketone/1-propanol (in 7/3 volume ratio) solution, initiated and catalyzed by ethyl 2-bromopropionate(BRA)/CuCl/2,2'-bipyridine(BPY). Polymer of GMA with planned molecular weight and narrow molecular weight distribution was obtained. In case of bulk polymerization with the same initiator and catalyst the molecular weight of the polymer obtained was 1.5~2.1 times greater than that of the above one. By using 1-phenylethyl chloride(PECl)/CuCl/BPY as catalyst controlled ATRP of GMA has failed whether it was in bulk or in solution.
- glycidyl methacrylate,
- atom transfer radical polymerization,
- living polymerization
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