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Citation: Roderic P. QUIRK, Taejun YOO, Tae-Hee. CHEONG, Youngjoon LEE. Anionic Synthesis of Primary and Secondary Amine-Functionalized Polymers Using Imine Chemistry[J]. Chinese Journal of Applied Chemistry, ;2001, 18(5): 289-295. shu

Anionic Synthesis of Primary and Secondary Amine-Functionalized Polymers Using Imine Chemistry

1.
Maurice Morton Institute of Polymer Science, The University of Akron, Akron, Ohio, 44325-3909, U.S.A.

Received Date: 29 December 2000
Available Online: 3 February 2001

A review of methods for the anionic synthesis of well-defined, amine-functionalized polymers using imines as functionalizing agents is provided. The disparate results in the literature regarding functionalizations with N-(benzylidene)trimethylsilylamine to form primary amine functionalized polymers are discussed; the efficiency of functionalization depends on the molecular weight of the polymeric organolithium (PLi). Efficient functionalizations are observed for PLi with M_n>10 000 g/mol. The poor functionalization yields using ketimines with enolizable hydrogens is explained. The use of N-trimethylsilyldiphenylcarbimide as a quantitative primary amine functionalizing reagent is described. Recent results on the anionic synthesis of secondary amine-functionalized polymers using N-(benzylidene)methylamine as the functionalization agent are presented.
- amine-functionalized polymer,
- anionic synthesis,
- imine derivative,
- review
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