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Citation: LI Zai-Feng, LUO Fu-Ying. Synthesis and Antiseptic Property of E-and Z-2'-(1-Imidazolyl)-O-(α-methyl-dichlorobenzyl)-2, 4-dichloroacetophenoxime Nitrate[J]. Chinese Journal of Applied Chemistry, ;2001, 18(6): 473-476. shu

Synthesis and Antiseptic Property of E-and Z-2'-(1-Imidazolyl)-O-(α-methyl-dichlorobenzyl)-2, 4-dichloroacetophenoxime Nitrate

LI Zai-Feng ,
LUO Fu-Ying

1.
Center of Science and Technology, Zhanjiang Normal College, Zhanjiang 524048

Received Date: 22 August 2000
Available Online: 8 January 2001
Fund Project:

E-and Z-2'-(1-imidazolyl)-2,4-dichloroacetophenoxime isomers have been prepared starting from m-dichlorobenzene chloroacetyl chloride?imidazole by different feeding order in oximation and introduction of imidazolyl groups. T-Chloro-dichloroethlybenzene (Ⅱ_A~Ⅱ_c) were synthesized from m-, p- and o-dichlorobenzene. And six E-and Z-target compounds were synthesized in yield 57.5%~64.5% by reactions of Ⅰ and Ⅱ, respectively. Their structures were characterizated by elemental analysis, IR and ¹H NMR. The preliminary tests showed that the Z isomers of the title compounds had more or less higher antiseptic effect on the roting of rice roots.
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