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Citation: XU Hai, YU Dao-Yong, WANG Zong-Xian, Que Guo-He. Thermal Stability and Decomposition Kinetics of Some Metalloporphyrins[J]. Chinese Journal of Applied Chemistry, ;2001, 18(6): 447-449. shu

Thermal Stability and Decomposition Kinetics of Some Metalloporphyrins

1.
College of Chemistry and Chemical Engineering, University of Petroleum, Dongying 257061

Received Date: 12 September 2000
Available Online: 9 January 2001

The thermal stability and thermal decomposition kinetics of four metalloporphyrins: Ni-OEP, VO-OEP, Ni-TPP, VO-TPP(OEP:2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine; TPP:5,10,15,20-tetraphenyl-21H,23H-porphine) have been investigated. The thermal stability order of the four metalloporphyrins in N₂ is found to be: VO-TPP≈Ni-TPP> VO-OEP> Ni-OEP. The thermal decom position kinetics parameters of metalloporphyr ins are evaluated.
- metalloporphyrins,
- thermal stability,
- thermogravimetric analysis,
- kinetics
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