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Citation: GAO Zhu-Lin, YIN Cai-Xi, LI Quan, LIU Fu-Chu, ZHU Hong-You. Synthesis of (±)-Frontalin, an Aggregation Pheromone of Bark Beetle[J]. Chinese Journal of Applied Chemistry, ;2001, 18(7): 589-591. shu

Synthesis of (±)-Frontalin, an Aggregation Pheromone of Bark Beetle

1.
Department of Chemistry, Yunnan University, Kunming 650091

Received Date: 26 October 2000
Available Online: 2 April 2001
Fund Project: 云南省应用基础研究基金资助课题(98C017M) (98C017M)

(±)-Frontalin (1,5-dimethyl-6,8-dioxabicycl octane), an aggregation pheromone of bark beetle, was prepared from cyclohexanone via a key intermediate 6-hepten-2-one prepared by catalytic decarbonylation of 7-oxo-octanoic acid with acetic anhydride using palladium(Ⅱ) complex as catalyst.The structures of all the compounds were confirmed by IR, MS, ¹H NMR and ¹³C NMR.
- dendroctonus frontalis,
- aggregation pheromone,
- frontalin,
- synthesis
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