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Citation: FANG Bin, WANG XiN-Ling, TANG Xiao-Zhen, ZHU PiN-Fang. Preparation of Single-ionic Solid Electrolyte: Sodium Sulfonate-Poly(ethylene oxide)/Polyurethane and Its Ionic Conductivity[J]. Chinese Journal of Applied Chemistry, ;2001, 18(7): 521-523. shu

Preparation of Single-ionic Solid Electrolyte: Sodium Sulfonate-Poly(ethylene oxide)/Polyurethane and Its Ionic Conductivity

1.
a Faculty of Chemistry and Chemical Engineering, Jiaotong University, Shanghai 200240;
2.
b Analysis and Test Center, Jiaotong University, Shanghai

Received Date: 12 September 2000
Available Online: 8 June 2001
Fund Project: 国家自然科学基金项目(59903004) (59903004)

The sulfonated poly(ethylene oxide)sulphate/polyurethane mixture was prepared from polyethylene oxide, 1,4-butanediol and methylene-bis(4-phenyl isocyanate).The samples were characterized by FT-IR and elemental analysis.The ionic conductivity was calculated based on the impedance measurements.The relation of the conductivity with ion concentration, sulfonated polyether content and temperature were discussed.The conductivity of 2.5×10^-6 S/cm for the polymer electrolyte was obtained at room temperature.
- sulfonated poly(ethylene oxide)sulphate,
- polyurethane,
- ionic conductivity,
- solid polymer electrolyte
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