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Citation: MEI Fu-Ming, LI Guang-Xing, XU Hui-Bi. Synthesis of Diphenyl Carbonate by Oxidative Carbonylation of Phenol over PdCl₂-Mn(OAc)₂ Catalyst[J]. Chinese Journal of Applied Chemistry, ;2001, 18(9): 752-754. shu

Synthesis of Diphenyl Carbonate by Oxidative Carbonylation of Phenol over PdCl₂-Mn(OAc)₂ Catalyst

1.
Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074

Received Date: 23 November 2000
Available Online: 20 March 2001
Fund Project: 湖北省科学技术厅重点科技攻关项目(991P0315) (991P0315)

The oxidative carbonylation of phenol to diphenyl carbonate catalyzed by Pd-Co, Pd-Cu and Pd-Mn catalyst systems has been studied with the addition of other components such as benzoquinone, Bu₂NBr and molecular sieve.The results show that Bu₂NBr plays a very important role and Pd Mn catalyst has the highest activity among the three kinds of the catalysts studied.When the reaction is catalyzed by PdMn catalyst at n(PdCl₂):n(Mn(OAc)₂):n(Bu₄NBr):n(benzoquinone)=1:1:10:25, t=100℃, P=2.5 MPa(PCO/PO₂=4:1), reaction time 8 h, the yield of DPC is 7.23%.The yield of DPC is found to be increased with increase in total pressure of reactor and could be reached to 10.20% at total pressure of 3.5 MPa.
- diphenyl carbonate,
- oxidative carbonylation,
- PdCl₂-Mn(OAc)₂ catalyst
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Synthesis of Diphenyl Carbonate by Oxidative Carbonylation of Phenol over PdCl₂-Mn(OAc)₂ Catalyst