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Citation: WANG Xiao-Ping, WANG Jun-Wen, HE Ming-Wei, ZHANG Yong, PAN Jing-Hao. Synthesis and Electrochemical Property of the Zn-meso-tetrakis(p-methoxyl)phenylporphyrin[J]. Chinese Journal of Applied Chemistry, ;2001, 18(9): 713-716. shu

Synthesis and Electrochemical Property of the Zn-meso-tetrakis(p-methoxyl)phenylporphyrin

1.
a Department of Chemistry, Shanxi University, Taiyuan 030006;
2.
b Department of Chemistry, Shanxi Normal University, Lingfen

Received Date: 19 December 2000
Available Online: 5 June 2001
Fund Project: 国家自然科学基金(20045001) (20045001)山西省自然科学基金(981012)的资助项目 (981012)

meso-Tetrakis(p-methoxyl)phenylporphyrin(T(p-OCH₃)PP) and its Zn-complex (Zn-T(p-OCH₃)PP) were synthesized and characterized by elemental analysis,¹H NMR, UV and fluorescence spectra.The electrochemical properties of the complex have been investigated by cyclic voltammetry, electrocapillary method in DMSO and a tentative mechanism of reduction on the mercury electrode has been proposed.It is found that the peak currents of the complex are an irreversible adsorption wave.The adsorbed amount of T(p-OCH₃)PP and Zn T(p-OCH₃)PP on mercury electrode surface were 1.41×10^-10 and 6.77×10^-11 mol/cm², respectively as determined by chronoculometry.
- Zn-meso-tetrakis(p-methoxyl)phenylporphyrin,
- zinc-porphyrin complex,
- synthesis,
- electrochemical property
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