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Citation: LUO Yi-Fan, AN Bao-Li, MAI Kan-Cheng, SHI Jian-Xin, ZHANG Hong-Jie, GONG Meng-Lian. Preparation and Fluorescence of Sodium Tris(pyridine dicarboxylato) Europate(Ⅲ) Incorporated in Polycarbonate Resin[J]. Chinese Journal of Applied Chemistry, ;2001, 18(9): 709-712. shu

Preparation and Fluorescence of Sodium Tris(pyridine dicarboxylato) Europate(Ⅲ) Incorporated in Polycarbonate Resin

1.
a State Key Laboratory of Ultrafast Laser Spectroscopy, Zhongshan University, Guangzhou 5102510275;
2.
b School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou 510275;
3.
c Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun

Received Date: 29 December 2000
Available Online: 23 April 2001
Fund Project: 广东省自然科学基金研究团队项目(2000年) (2000年)

The strong fluorescence and high thermal stability of sodium tris(pyridine dicarboxylato)europate(Ⅲ), Na₃Eu(DPA)₃, were used for modification of polycarbonate(PC) resin.The polycarbonate resin composite was prepared at 220℃ for 30 min under stirring.The excitation and emission spectra and thermogravimetric analysis results showed that the prepared Na₃Eu(DPA)₃-PC composite material retained the fluorescence characteristics and strong red emission of the Eu³⁺chelate and its fluorescence intensity was found to be increased with increase in the mass fraction of Na₃Eu-(DPA)₃ in PC resin, but did not in linear relation.
- rare earth complex,
- Na₃Eu(DPA)₃,
- polycarbonate resin,
- fluorescence,
- composite material
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