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Citation: YANG Tian-Lin, YANG Yong-Hui, SUN Si-Siu. The Interfacial Properties of Primary Amine N₁₉₂₃ in Different Diluents[J]. Chinese Journal of Applied Chemistry, ;2001, 18(9): 697-700. shu

The Interfacial Properties of Primary Amine N₁₉₂₃ in Different Diluents

1.
a Department of Chemistry, Ningxia University, Yinchuan 750021;
2.
b Department of Chemistry, Shandong University, Jinan

Received Date: 10 November 2000
Available Online: 23 April 2001
Fund Project: 国家自然科学基金资助项目(29671022) (29671022)

The interfacial properties of primary amine N₁₉₂₃ in different diluents 0.1 mol/L (H,Na)NO₃ (pH=2.34) liquid/liquid systems have been studied.The interfacial parameters, c_min and A_I, of N₁₉₂₃ have been obtained.It was suggested that the monomeric N₁₉₂₃ molecule was the active species adsorbed at the interface.The interfacial activity of N₁₉₂₃ in different systems decreased as follows: n-heptane, cyclohexane, benzene, toluene, carbon tetrachloride, chloroform, isoamyl acetate and methyliso-butylketone(MIBK).This results were possibly due to the interaction between diluents and extractant, extractant and water molecules near interfacial layer, and diluents and water molecules near interfacial layer.The relationship between the interfacial properties and extraction reaction have also been discussed.
- primary amine N₁₉₂₃,
- diluents,
- interfacial property,
- extraction
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The Interfacial Properties of Primary Amine N₁₉₂₃ in Different Diluents