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Citation: LI Qiu-Xiao, ZHANG Gao-Yong, PENG Shao-Yi. The Cu-Ni-Mg Catalysts for Catalytic Amination of Dodecyl Alcohol[J]. Chinese Journal of Applied Chemistry, ;2001, 18(9): 693-696. shu

The Cu-Ni-Mg Catalysts for Catalytic Amination of Dodecyl Alcohol

1.
a China Research Institute of Daily Chemical Industry, Taiyuan 030001;
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b Shanxi Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan

Received Date: 18 October 2000
Available Online: 19 January 2001

The effects of addition of Mg to CaCO₃ supported Cu-Ni catalyst in catalytic amination of dodecyl alcohol with dimethylamine have been investigated.It is found that Mg can effectively promote the selectivity of the catalyst due to its prohibition effect on the reduction of Ni.The XPS results of the catalysts revealed that Ni in the catalyst with added Mg has a relatively higher positive charge.The higher the positive charge of Ni, the higher the selectivity of the catalysts.
- lauryl alcohol,
- catalytic amination,
- Cu-Ni-Mg catalysts
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