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Citation: LI Jian, LIN Ming-De, HUANG Li-Zhong. Copolymerization of Tert-butyl 3-isopropenyl-cumylperoxide and Vinyl Acetate[J]. Chinese Journal of Applied Chemistry, ;2001, 18(12): 991-993. shu

Copolymerization of Tert-butyl 3-isopropenyl-cumylperoxide and Vinyl Acetate

1.
Department of Chemical Engineering, Jiangsu Institute of Petrochemical Techonogy, Changzhou 213016

Received Date: 20 January 2001
Available Online: 20 July 2001
Fund Project: 江苏省自然科学基金资助项目(BK99115) (BK99115)

The copolymerization of tert-butyl-3-isopropenylcumylperoxide(D120) with vinyl acetate has been studied.The copolymer with pendant peroxide groups was obtained by the free radical poly-merization. The Mn of the copolymers were about 12 000~14 000 and did not changed with the D120 content in the comonomers. It was found that the decomposition temperature of the peroxide group in the copolymers decreased with the increase in content of D120 units in the copolymer. The reactivity ratio based on Kelen-Tudos method was measured to be: r_D120=0.0126,r_VAC=2.39. The effect of the amount of D120 units in copolymers on tensile strength of copolymer film were investigated also.
- tert-butyl-isopropenylcumylperoxide,
- vinyl acecate,
- copolymerization,
- reactivity ratio,
- polymeric peroxide
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