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Citation: DONG Qi-Gong, ZHANG Jun-Ping, LI Ya-Rong. Synthesis and Adsorption Property of Polythioether Cellulose Compound[J]. Chinese Journal of Applied Chemistry, ;2002, 19(1): 94-96. shu

Synthesis and Adsorption Property of Polythioether Cellulose Compound

1.
Department of Chemistry, Northwest University, Xi'an 710069

Corresponding author: DONG Qi-Gong,
Received Date: 17 May 2001
Available Online: 6 August 2001
Fund Project: 陕西省自然科学基金资助项目(98C29) (98C29)

A kind of polythioether cellulose compound(PTEC) was synthesized by etherification of rice husk cellulose with chloromethylthiirane(CMT) in alkaline media. The preparation conditions have been investigated. The PTEC with 4.31% sulfur content was obtained by reacting 12 g rice husk cellulose with 36 mL chloromethylthiirane in 3 mol/L NaOH solution. The product has an adsorption capacity for Ag(Ⅰ) and Hg(Ⅱ) of 24.92 mg/g and 66.80 mg/g, respectively at pH=7 and for Pb(Ⅱ) it is 0.15 mg/g at pH=3. The fiber could be used as a adsorbent for metal ions.
- rice husk cellulose,
- chloromethylthiirane,
- metal ion,
- adsorption
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