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Citation: CHEN Sheng-Zhou, LI Yan, CHEN Zu-Xing. Synthesis of (S)-2-Acetoxyltridecane by Enzymatic Reduction of β-Ketoester[J]. Chinese Journal of Applied Chemistry, ;2002, 19(1): 85-87. shu

Synthesis of (S)-2-Acetoxyltridecane by Enzymatic Reduction of β-Ketoester

1.
Faculty of Chemistry and Materials Science, Hubei University, Wuhan 430062

Corresponding author: LI Yan,
Received Date: 17 May 2001
Available Online: 13 August 2001
Fund Project: 湖北省科委自然科学基金资助项目(97j075) (97j075)

(S)-2-Acetoxyltridecane, which is the aggregation pheromone of Drosophila Mulleric and the sex pheromone component of the pea midge (Contarinia pisi), was synthesized from ethyl acetoacetate by enzymatic reduction with baker's yeast in the presence of ethyl chloroacetate as a key step. The optical purity of the target product is about 98%e.e.
- (S)-acetoxyltridecane,
- enzymatic reduction,
- synthesis,
- pheromone
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