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Citation: LIAO Chuan-Ping, GU Ming-Yuan. Autocatalytic Polymerization of Aniline on Quartz Crystal Microbalance[J]. Chinese Journal of Applied Chemistry, ;2002, 19(1): 80-81. shu

Autocatalytic Polymerization of Aniline on Quartz Crystal Microbalance

LIAO Chuan-Ping ^, ,
GU Ming-Yuan

1.
State Key Laboratory for MMCs, Shanghai Jiaotong University, Shanghai 200030

Corresponding author: LIAO Chuan-Ping,
Received Date: 22 April 2001
Available Online: 20 September 2001
Fund Project: 国家自然科学基金资助项目(59971038) (59971038)

Quartz crystal microbalance(QCM) was used to study the autocatalytic polymerization of aniline. The deposition of polyaniline film via autocatalytic polymerization onto a Pt quartz crystal causes the decrease in oscillation frequency of the crystal in QCM, thereby the mass of the film is determined. The experimental results show that the catalytic activity of Pt substrate is much stronger than that of the polyaniline film on the autocatalytic polymerization. The rate of the autocatalytic polymerization falls down gradually with the time and reaches a steady value finally. The film can reach about 0.17 μm after 24 hours'deposition.
- polyaniline,
- autocatalytic polymerization,
- quartz crystal microbalance
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