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Citation: TAO Ruo-Jie, LOU Ben-Yong, ZANG Shuang-Quan, ZHOU Xu-Ya, WANG Qing-Lun, LIAO Dai-Zheng. Sythesis,Electrochemical and Magnetic Properties of Heterobinuclear Complexes Bridged by N-(2-Carboxy phenyl)-N'-(3-aminopropyl) oxamide[J]. Chinese Journal of Applied Chemistry, ;2002, 19(1): 43-47. shu

Sythesis,Electrochemical and Magnetic Properties of Heterobinuclear Complexes Bridged by N-(2-Carboxy phenyl)-N'-(3-aminopropyl) oxamide

1.
a Chemistry and Chemical Engineering College, Henan University, Kaifeng 475001;
2.
b Department of Chemistry, Nankai University, Tianjin

Corresponding author: TAO Ruo-Jie,
Received Date: 17 May 2001
Available Online: 8 October 2001
Fund Project: 河南省教委资助课题(99150024) (99150024)

Four novel heterobinuclear complexes have been synthesized,[Cu(oxca)M(phen)₂]ClO₄·2H₂O where oxca=N-(2-carboxy phenyl)-N'-(3-aminopropyl) oxamide; phen=1,10-phenanthroline; M=Mn²⁺, Co²⁺, Ni²⁺, Zn²⁺. The results obtained from IR、elemental analysis、thermogravimetric analysis conductivity, electronic spectrum and room temperature magnetic moment measurements showed these complexes appeared to have extended oxamido-bridged structures. The electrochemical properties of the heterobinuclear complexes have been measured by cyclic votammetry in DMSO. The temperature dependence of the magnetic susceptibility of Cu(Ⅱ)-Mn(Ⅱ) and Cu(Ⅱ)-Ni(Ⅱ) over the range 4~300 K gave the exchange integral of J=-10.56 cm^-1 and J=-17.08 cm^-1.
- dissymmetrical oxamide,
- cyclic voltammetry,
- antiferromagnetic interaction
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