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Citation: CAI Hong, ZHANG Li, ZHUO Xin, WANG Hong-Yan, WANG Jian-Hua, LI Wei-Hua, CAI Sheng-Min. Study on TiO₂/CdS/Ru(bpy)₂(NCS)₂ as Photoanode of Solarcell[J]. Chinese Journal of Applied Chemistry, ;2002, 19(1): 38-42. shu

Study on TiO₂/CdS/Ru(bpy)₂(NCS)₂ as Photoanode of Solarcell

1.
a Suzhou Teacher's College, Suzhou 234000;
2.
b College of Chemistry and Molecular Engineering, Peking University, Beijing

Corresponding author: ZHANG Li,
Received Date: 19 July 2001
Available Online: 10 November 2001
Fund Project: 安徽省教委自然科学基金资助项目(99j10211) (99j10211)

The CdS nanoparticles were formed in the holes of a TiO₂ nanoporous film, named as TiO₂/CdS composite semiconductor nanoporous film. The films were then sensitized by Ru(bpy)₂(NCS)₂. The conversion efficiency of light to electricity for the TiO₂/CdS/Ru(bpy)₂(NCS)₂ composite semiconductor nanoporous films was investigated as function of the deposition time of CdS on TiO₂ and it was proved that the efficiency was dependent on the depositing time. When CdS was deposited on TiO₂ for five minutes. The resulting cell had an energy conversion efficiency of 0.77%, with open circuit voltage of 0.716 V and short circuit current density of 5.23 A/m².
- light-to-electricity conversion efficiency,
- composite semiconductor nanoporous film electrode,
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Study on TiO₂/CdS/Ru(bpy)₂(NCS)₂ as Photoanode of Solarcell