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Citation: ZU Feng-Hua, LIU Yan-Qin, HAN Shi-Tian. Catalytic Asymmetric Epoxidation of Styrene Using Manganese Tetrachlorophenylporphyrin Complexes[J]. Chinese Journal of Applied Chemistry, ;2002, 19(2): 184-186. shu

Catalytic Asymmetric Epoxidation of Styrene Using Manganese Tetrachlorophenylporphyrin Complexes

1.
College of Chemistry, Hebei Normal University, Shijiazhuang 050091

Corresponding author: LIU Yan-Qin,
Received Date: 11 April 2001
Available Online: 16 November 2001
Fund Project: 河北省自然科学基金资助课题(299194) (299194)

Three complexes of tetrachlorophenylporphyrinatomanganese acetates have been synthesized and characterized by IR and UV spectra. The asymmetric epoxdation of styrene has been investigated by using these three complexes as catalysts, chiral quaternary ammonium salts as phase transfer catalysts, and quinine as chiral auxiliary, sodium hypochlorite as oxidant. The results showed that the structure of manganese porphyrins, the chiral auxiliaries and temperature of reaction affected the asymmetric induction. The best enantiomer excess reached 12.8%.
- metalloporphyrin,
- asymmetric epoxdation,
- catalyst,
- enantiomer excess
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