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Citation: LI Wen-Xian, ZHANG Dong-Feng. Synthesis and Characterization of Phenylcarboxymethyl-sulfoxide Complexes with Lanthanide and Study on Fluorescence Spectrum of Eu(Ⅲ) Complex[J]. Chinese Journal of Applied Chemistry, ;2002, 19(2): 140-143. shu

Synthesis and Characterization of Phenylcarboxymethyl-sulfoxide Complexes with Lanthanide and Study on Fluorescence Spectrum of Eu(Ⅲ) Complex

LI Wen-Xian ^, ,
ZHANG Dong-Feng

1.
College of Chemistry and Chemical Industry, Inner Mongolia University, Hohhot 010021

Corresponding author: LI Wen-Xian,
Received Date: 17 July 2001
Available Online: 12 November 2001
Fund Project: 内蒙古自然科学基金资助项目(20001301) (20001301)

Six solid complexes of phenylcarboxymethyl sulfoxide(LH) with lanthanide(Ln=La,Ce,Pr,Nd,Sm,Eu) have been synthesized and characterized. Elemental analysis and ¹H NMR results suggested that the complexes have a composition of RELCl₂·3H₂O·1.5C₂H₅OH(RE=La,Ce,Pr,Nd,Sm,Eu). The molar conductivities of the complexes in aqueous solution indicated that Cl-anions are not coordinated. IR results indicated the ligand is bonded with RE³⁺ ions through two oxygen atoms in carboxyl group as a symmetrical chelating bidentate group and one oxygen atom in sulfoxyl group. Fluorescence spectrum of Eu³⁺ complex revealed that there is no inversion symmetry at the site of Eu³⁺ ion.
- phenylcarboxymethyl-sulfoxide,
- rare earth complex,
- synthesis,
- characterization,
- fluorescence
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