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Citation: CAI Ming-Zhong, LIU Xiao-Ling, XU Hai-Yun, LI Wei. Synthesis and Characterization of Polyether ketone ether ketone ketones Containing Naphthalene Ring[J]. Chinese Journal of Applied Chemistry, ;2002, 19(6): 591-593. shu

Synthesis and Characterization of Polyether ketone ether ketone ketones Containing Naphthalene Ring

1.
Institute of Chemistry and Biological Science, Jiangxi Normal University, Nanchang 330027

Corresponding author: CAI Ming-Zhong,
Received Date: 8 October 2001
Available Online: 21 February 2002
Fund Project: 国家"863"计划(863-715-15-01-04) (863-715-15-01-04)江西省自然科学基金资助项目(990308) (990308)

Polyether ketone ether ketone ketones containing naphthalene ring were synthesized by low temperature solution polycondensation of 4,4'-bis(T-naphthoxy)benzophenone(DNBP), terephthaloyl chloride(TPC) and isophthaloyl chloride(IPC) in 1,2-dichloroethane and in the presence of AlCl₃ and NMP. The polymers obtained were characterized by IR, DSC, TG, and WAXD methods. The results show that the polymers are non crystalline, soluble in NMP, DMF, and 1,2-dichloroethane(DCE), and have high glass transition temperature and good heat resistance.
- polyether ketone ether ketone ketone,
- synthesis,
- phthaloyl chloride
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