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Citation: WU Ling, CHEN Hong Yu, DAI Guang Hong, LIANG Jie, JIANG Xiong. Influence of Bismuth(Ⅲ) in Sulfuric Acid Electrolyte on the Cathode Behavior of Lead-acid Battery[J]. Chinese Journal of Applied Chemistry, ;2002, 19(6): 574-577. shu

Influence of Bismuth(Ⅲ) in Sulfuric Acid Electrolyte on the Cathode Behavior of Lead-acid Battery

1.
Department of Chemistry, South China Normal University, Guangzhou 510631

Corresponding author: WU Ling,
Received Date: 18 September 2001
Available Online: 6 March 2002

The influence of Bi³⁺ ions in sulfuric acid electrolyte on the cathode behavior of lead-acid battery has been investigated by cyclic voltammetry(CV), cathodic polarization and electrochemical impedance spectroscopy(EIS). The results demonstrated that bismuth ion can be deposited on the cathode surface in the course of charging, resulting in the decrease of both cathode hydrogen overpotential and discharge capacity. The deposition of bismuth ions due to ion displacement may also lead to a quick formation of PbSO₄ film on the electrode surface. The thickened PbSO₄ film might retard the migration of H⁺ and HSO₄^- ions, decreasing the self-discharge of battery at open potential.
- lead-acid battery,
- sulfuric acid,
- cathode behavior,
- bismuth ion
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