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Citation: LIU Jing-Qin, ZHANG Li, ZHU Zhi-Bo, LIU Yi. Synthesis of Organosilicone-Modified Acrylates Latexes[J]. Chinese Journal of Applied Chemistry, ;2002, 19(6): 569-573. shu

Synthesis of Organosilicone-Modified Acrylates Latexes

1.
Department of Chemistry, South China Normal University, Guangzhou 510631

Corresponding author: ZHANG Li,
Received Date: 10 September 2001
Available Online: 6 March 2002
Fund Project: 广东省科委重点攻关(2KM03010S) (2KM03010S)广州市科委高新技术(2000-Z-086-01)资助项目 (2000-Z-086-01)

The acrylate copolymer latexes modified with organosilicone were prepared by seeding emulsion copolymerization in the presence of peroxide and complex redox initial system. When m(MMA):m(BA)=55:43, k(Si)=8%~16%,K(emulsifier)=4% and k(initiater)=0.5% an emulsion of good property for coatings could be obtained. The structures of copolymers characterized by FTIR and DSC showed that it is a copolymeration between organosilicone and acrylates, neither hydrolyzation nor condensation occurred in latexes.
- acrylate,
- organosilicone,
- emulsion copolymerization,
- coating
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