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Citation: Tang Zhi-uan, WANG Zhan-Liang, XUE Jian-Jun, LIU Chun-Yan. Influence of Plasticizers on Polymer Electrolyte Lithium Ion Battery[J]. Chinese Journal of Applied Chemistry, ;2002, 19(6): 560-563. shu

Influence of Plasticizers on Polymer Electrolyte Lithium Ion Battery

1.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072

Corresponding author: Tang Zhi-uan,
Received Date: 30 August 2001
Available Online: 30 December 2001

The influences of plasticizers EC(ethylene carbonate), DME(dimethoxy ethane), DEC(diethyl-carbonate), EMC(methyl ethyl carbonate) and PC(propylene carbonate) in various combination on the conductivity and performance of gelled polymer electrolytes at different temperatures have been investigated as functions of charge-discharge properties of LiCoO₂ and graphitized carbon fiber. The highest conductivity of gel polymer electrolyte was obtained with plasticizers EC-DME as 0.188 S/m at room temperature. The first discharge specific capacity of LiCoO₂ with combination plasticizer was about 145 mA·h/g, and the effect of plasticizer is not obvious. The discharge specific capacity of graphitized carbon fiber in EC DEC EMC was 300 mA·h/g, with the initial coulomb efficiency being about 95%.
- polymer electrolyte,
- lithium ion battery,
- carbon fiber,
- LiCoO₂
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